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Presumably, the “she” Milady refers to is Madame Bonacieux, although it is not clear whether Athos knows this. Athos’s rage is sparked by Milady’s defiance, which he finds infuriating. It seems likely that there was more to their marriage that Athos never disclosed to d’Artagnan, and that the reader never finds out. Although he would like to rid himself of Milady once and for all, Athos acts with his brain rather than his emotions and dooms Milady’s mission by stealing her letter from the cardinal.